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In the match between Grigor Dimitrov and Vít Kopriva, Grigor has the best chances of winning. He has an advantage in serving, which can be a decisive factor in the Madrid tournament. Additionally, he is in good form and has not had major setbacks in his performances. On the other hand, Vít Kopriva has shown inconsistent results and may make mistakes in matches. Taking these factors into account, it is more likely that Grigor Dimitrov will emerge as the winner in this encounter.